PARTIAL PRESSURE CONCEPTS
1. All gases exert pressure on their surroundings.
2. The pressures exerted by individual
gases in the same vessel are independent of each
other.
3. Dalton's Law: The partial
pressure of a gas in a gas mixture is the pressure the
gas would exert
if it occupied the total volume of the mixture in the absence of the other
components.
4. The partial pressures of all gases
in a gas mixture can be summed to give the total pressure
of the mixture.
Example: Ambient air contains 21% oxygen (O2) and 78% nitrogen (N2).
If atmospheric pressure = 760 mmHg, then
Po2 = 760 x 0.21 = 160 mmHg
PN2 = 760 x 0.78 = 593 mmHg
The sum of
the partial pressures of oxygen, nitrogen, carbon dioxide (CO2),
and all
other gases in ambient air is 760 mmHg.
5. The number of gas molecules
which dissolve in a liquid is proportional to the partial
pressure
of the gas.
6. Henry's Law: The concentration
of a gas dissolved in a liquid is proportional to its
partial pressure.
7. The proportionality constant is the solubility of the gas in the liquid.
8. At equilibrium, the partial
pressure of a gas in solution is equal to its partial pressure in
the gas mixture.
Example: Solubility of oxygen in blood = 0.003 ml O2/100 ml blood/mmHg Po2
If Po2
= 100 mmHg, then the concentration of oxygen dissolved in blood
=
100 x 0.003 = 0.3 ml O2/100 ml blood.
Updated 11/25/01