CHEMISTRY 2440
Organic Chemistry I
Spring 2002 - 11:00-11:50am - MWF - PS4020
Dr. T. Howard Black
Office: Physical Science 4440
Telephone: 581-6225
Office Hours: 9:30-10:30am T; 10-11am R; 3-4pm MWF
Email: cfthb@eiu.edu
Class Homepage: http://www.ux1.eiu.edu/~cfthb/classes/2440

Texts:
1. T.W.G. Solomons and C.B. Fryhle, Organic Chemistry, 7th Edition, John Wiley & Sons, Inc., 2000.
2. "Solutions Manual and Study Guide" (for above).

Schedule

The following schedule is approximate, although we'll try to follow it as closely as possible. We will stay with the exam dates regardless of where we stand with our coverage of the material, so that you will always know when exams will occur.
 

Week
Beginning
Chapter(s)
Topics
1/17
1
Carbon Compounds and Chemical Bonds
1/14
2 (2.3, 2.4)
Covalent Bonds (polar/nonpolar); Polar/Nonpolar Molecules
1/21
3 (3.2-3.10)
An Introduction to Organic Reactions: Acids and Bases
1/28, 2/4
4
Alkanes: Nomenclature, Conformational Analysis, and an Introduction to Synthesis

Exam I - Wednesday, February 6, 2002


2/11
5
Stereochemistry: Chiral Molecules
2/18
6
Ionic Reactions - Nucleophilic Substitution and Elimination Reactions of Alkyl Halides
2/25
7
Alkenes and Alkynes I: Properties and Synthesis. Elimination Reactions of Alkyl Halides

Exam II - Monday, March 4, 2002


3/4, 3/18
8
Alkenes and Alkynes II: Addition Reactions
3/25
9
Nuclear Magnetic Resonance and Mass Spectrometry: Tools for Structure Determination
4/1
10
Radical Reactions
4/8
11
Alcohols and Ethers

Exam III - Friday, April 12, 2002


4/15
12
Alcohols from Carbonyl Compounds. Oxidation-Reduction and Organometallic Compounds

  Final Exam - Wednesday, 5/1/02, 1015am - 1215pm



Grading

    Selected problems from the end of each chapter are provided at the end of this document. These exercises, the answers to which are supplied in the Study Guide Problems Book, will be neither collected nor graded. You are strongly encouraged to work through these problems, in addition to those on the handouts which may occasionally be supplied. This is by far the most efficient and time-proven way to learn the concepts so vital to understanding organic chemistry.

    There will be 12 or more quizzes (10 points each) throughout the semester; quizzes are always announced at least one class day before they are given. The scores of only the highest ten will be used in the final grade calculation; thus, the quiz total is 100 points. There will be no makeup quizzes for any reason. FYI, the average number of quizzes for this course is 14-17.

    Three one-hour exams (100 points each) will be evenly spaced over the term; the dates are given on the schedule. If you are going to miss an hour exam (for an extremely good reason - documented,1 serious illness or family death), be sure and let me know ahead of time, or, at the very latest, before the end of the day on which the exam was given. There is no provision for making up an exam.

    The keys to quizzes and exams will appear on the course's website by the end of the quiz/exam day.  Barring some unforeseen complication, the graded quizzes/exams will be returned on the class day following the quiz/exam.

    The final examination will be comprehensive, covering all topics discussed during the term; it will be worth 200 points. Thus, the point total available for the course equals 600.  Final exams are not returned, although you are welcome to stop in at any time subsequent to your exam's being graded to look at it and compare it to the key.  Final exams are shredded on the day after the last day for grade appeals in the following semester.

    Grades will be assigned based on a curve related to class performance as a whole; thus, individual quizzes and exams will not receive letter grades. The curve will be updated throughout the semester after each exam, and will be announced during the class when graded exams are returned, in addition to being posted on the web page. You are encouraged to stop in my office at any time during the semester to see where you stand.

    After the third exam, the overall curve for the semester will be finalized. In other words, the curve announced after the third exam will not change for the rest of the course.  A great advantage for you is that, going into the final exam, you will know exactly how many points are needed to earn a certain grade. If the class average on the final is unusually low, the curve may be lowered. However, you are promised that, in the event that the class does much better on the final than usual, the curve will not be raised.

    For instance, if you calculate that you need 130 points out of 200 (65%) to earn an "A", I guarantee that, if you earn the 130, you'll get the "A".  It could be that the class would do poorly on the final and I'd lower the curve, such that you need only 125 points instead of 130 for your "A".  But it will not require more than 130 if the class does extremely well on the final - I will not raise the curve.

Additional Help

    The homepage for this class is located at the URL given at the start of this syllabus: http://www.ux1.eiu.edu/~cfthb/classes/2440.  As I do in other classes, I will publish the keys to quizzes/exams very quickly after you take them (usually within a day). I will also post additional interesting/useful information, including the current class curve, as the semester progresses.

    The keys to all of the quizzes and exams for the last (and first!) semester I taught this class are linked to the class homepage (and here).  Additionally, the quizzes/exams for the past four semesters of Chemistry 2430 (Survey of Organic Chemistry, which covers all of the 2440/2840 topics in a single semester) are linked (here, as well).  Although the pace is faster and the coverage less deep than in this class, the quizzes/exams will still provide very useful drill material for you.  I suggest that you visit and look around the homepage for this class very early this semester, to become familiar with the resources available there.

    It is the rare individual who can master organic chemistry purely by individual effort. You are encouraged to study with others, help each other with problems (after your own efforts have failed), and take advantage of the free tutoring offered by the Chemistry Department (tutoring schedule). Although my office hours are times when I guarantee to be available, please feel free to stop in at any time for help. You can also send me email or call to set up an appointment. I promise to give you all the help you are willing to ask for.

Suggested Problems

(Numbers in red are problems whose background we did not discuss in class, so some extra reading will be required for you to answer them.  But, remember: I will never test you on a concept that we did not discuss in class.)

Chapter 1 - 16, 17, 21, 26-30

Chapter 2 - 27 (f has an error; see box below), 33, 34, 35

Chapter 3 - 15, 19, 22, 28, 33, 36, 37

Chapter 4 - 20, 25, 29, 31, 37, 39, 41, 42, 44

Chapter 5 - 30, 33, 35, 38, 40

Chapter 6 - 13-15, 17, 20, 21, 25, 26, 30, 32, 33, 39, 42, 45

Chapter 7 - 19, 21, 22, 24, 26, 27, 33, 35, 37, 43, 48

Chapter 8 - 21-26, 28, 31, 37, 42, 48

Chapter 9 - 27, 29, 31, 35, 37

Chapter 10 - 19, 21, 25, 27

Chapter 11 - 31, 33-36, 39, 42, 44, 46

Chapter 12 - 11-13, 14ace, 15ace, 16a-d, 17efhim, 18adef, 19, 20, 22


1If you are too sick to take one of three important exams, you should be seen at the Health Center. Please show me the documentation from this visit when you return to class; since, without this documentation, there is no chance you'll be making up the exam.